Heterogeneous Catalysis in Sustainable Synthesis Advances in Green and Sustainable Chemistry 1st Edition by Bela Torok, Christian Schaefer, Anne Kokel 0128178264 9780128178263

Chapter 1: Heterogeneous catalysis for organic synthesis: Historical background and fundamentals

Abstract

1.1: Introduction and historical background

1.2: Catalysis

1.3: Conclusions and outlook

Chapter 2: Solid catalysts for environmentally benign synthesis

Abstract

2.1: Introduction

2.2: Metal catalysts

2.3: Nonmetallic catalysts

2.4: Conclusions and outlook

Chapter 3: Application of heterogeneous catalysis in the development of environmentally benign synthetic processes

Abstract

Chapter 3.1: Hydrogenation

Abstract

3.1.1: Introduction

3.1.2: Carbon-carbon multiple bond hydrogenations: Alkenes, alkynes, dienes

3.1.3: Hydrogenation of aromatic and heteroaromatic compounds

3.1.4: Reduction of carbonyl compounds by heterogeneous catalytic hydrogenation: Aldehydes, ketones, and carboxylic acid derivatives

3.1.5: Hydrogenation of nitrogen-containing groups: NO, NN, CN, and CN groups

3.1.6: Chemo- and regioselective hydrogenation of compounds with multiple hydrogenation sensitive groups

3.1.7: Heterogeneous catalytic hydrogenations by nonconventional activation methods

3.1.8: Conclusions and outlook

Chapter 3.2: Heterogeneous catalytic hydrogenolysis of organic compounds

Abstract

3.2.1: Introduction

3.2.2: CC bonds

3.2.3: CO bonds

3.2.4: CN bonds

3.2.5: C-halogen bonds—Dehalogenation

3.2.6: NN and NO bonds

3.2.7: CS bonds

3.2.8: Hydrogenolysis of C-other elements (Si, metals) bonds

3.2.9: Hydrogenolysis of biomass-related compounds

3.2.10: Conclusions and outlook

Chapter 3.3: Heterogeneous catalytic oxidations

Abstract

3.3.1: Introduction

3.3.2: Epoxidation reactions

3.3.3: Dihydroxylation reactions

3.3.4: Wacker-type oxidation reactions

3.3.5: Oxidative cleavage of hydrocarbons

3.3.6: Oxidation of CO and CN bonds

3.3.7: Dehydrogenation and aromatization of CC and CX bonds

3.3.8: Conclusions and outlook

Chapter 3.4: Metathesis by heterogeneous catalysts

Abstract

3.4.1: Introduction

3.4.2: Cross-metathesis

3.4.3: Ring-closing metathesis

3.4.4: Ring-opening metathesis

3.4.5: Alkyne metathesis

3.4.6: Heterogeneous catalytic asymmetric metathesis

3.4.7: Metathesis applied to bioderived alkenes

3.4.8: Conclusions and outlook

Chapter 3.5: Friedel-Crafts and related reactions catalyzed by solid acids

Abstract

3.5.1: Introduction

3.5.2: Alkylation, hydroxyalkylation

3.5.3: Acylation

3.5.4: Friedel-Crafts cycliacyalkylations

3.5.5: Halogenation

3.5.6: Nitration

3.5.7: Sulfonation

3.5.8: Conclusions and outlook

Chapter 3.6: Cross-coupling reactions for environmentally benign synthesis

Abstract

3.6.1: Introduction

3.6.2: The Heck coupling

3.6.3: The Suzuki coupling

3.6.4: The Hiyama coupling

3.6.5: The Negishi coupling

3.6.6: The Kumada coupling

3.6.7: The Sonogashira coupling

3.6.8: The Tsuji-Trost allylation

3.6.9: Coupling reactions not involving a CC bond formation

3.6.10: Conclusions and outlook

Chapter 3.7: Multicomponent reactions

Abstract

3.7.1: Introduction

3.7.2: Carbonyl-based multicomponent reactions

3.7.3: Isocyanide-based reactions

3.7.4: Conclusions and outlook

Chapter 3.8: Ring transformations by heterogeneous catalysis

Abstract

3.8.1: Introduction

3.8.2: Cyclization

3.8.3: Ring opening reactions

3.8.4: Conclusions and outlook

Chapter 3.9: Heterogeneous catalytic rearrangements and other transformations

Abstract

3.9.1: Rearrangements

3.9.2: Aldol and related reactions

3.9.3: Condensations

3.9.4: Hydrolysis

3.9.5: Introduction and removal of protecting groups

3.9.6: Hydroformylations

3.9.7: Conclusions and outlook

Chapter 3.10: Asymmetric synthesis by solid catalysts

Abstract

3.10.1: Introduction

3.10.2: Oxidation reactions

3.10.3: Hydrogenation

3.10.4: Aldol-reaction and related chemistry

3.10.5: Multicomponent and various other reactions

3.10.6: Conclusions and outlook

Index