Organic Chemistry 100 Must Know Mechanisms 1st edition by Roman Valiulin ISBN 3110608308 978-3110608304

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ISBN 10:  3110608308

ISBN 13:  978-3110608304

Author: Roman Valiulin

This book summarizes 100 essential mechanisms in organic chemistry ranging from classical such as the Reformatsky Reaction from 1887 to recently elucidated mechanism such as the copper(I)-catalyzed alkyne-azide cycloaddition. The reactions are easy to grasp, well-illustrated and underpinned with explanations and additional information.

Organic Chemistry 100 Must Know Mechanisms 1st Table of contents: 

1. Introduction to Organic Mechanisms

   • Overview of organic chemistry and reaction mechanisms
   • The importance of understanding reaction mechanisms
   • Key principles and terminology in organic mechanisms

2. Chapter 1: Nucleophilic Substitution Reactions (SN1 and SN2)

   • Mechanisms of SN1 and SN2 reactions
   • Factors affecting reaction rates
   • Examples and applications of nucleophilic substitution

3. Chapter 2: Elimination Reactions (E1 and E2)

   • E1 vs. E2 mechanisms
   • Regioselectivity and stereochemistry in elimination reactions
   • Examples of elimination reactions

4. Chapter 3: Addition Reactions

   • Electrophilic addition to alkenes
   • Hydrohalogenation, hydration, and halogenation
   • Mechanisms for addition to alkynes

5. Chapter 4: Radical Reactions

   • Radical initiation, propagation, and termination
   • Radical halogenation and polymerization
   • Mechanisms of radical reactions in organic chemistry

6. Chapter 5: Electrophilic Aromatic Substitution

   • Mechanism of electrophilic aromatic substitution
   • Common electrophiles in aromatic substitution
   • Examples like nitration, sulfonation, Friedel-Crafts reactions

7. Chapter 6: Nucleophilic Addition Reactions

   • Addition to carbonyl compounds (aldehydes, ketones)
   • Mechanism of hydride and alkyl addition
   • Examples in aldehyde and ketone chemistry

8. Chapter 7: Rearrangements and Other Reactions

   • Mechanisms of common organic rearrangements (e.g., Wagner–Meerwein, Beckmann, etc.)
   • Types of shift reactions and examples
   • Intramolecular reactions and their mechanisms

9. Chapter 8: Pericyclic Reactions

   • Mechanism of cycloaddition, electrocyclic, and sigmatropic rearrangements
   • The Woodward-Hoffmann rules
   • Examples like the Diels-Alder reaction

10. Chapter 9: Organometallic Reactions

    • Mechanisms of reactions involving organometallic reagents (Grignard, lithium reagents)
    • Cross-coupling reactions (e.g., Suzuki, Heck)
    • Role of transition metals in reaction mechanisms

11. Chapter 10: Enzyme-Catalyzed Mechanisms

    • Basics of enzyme-catalyzed reactions
    • Mechanisms of enzyme activity
    • Enzyme inhibitors and their roles

12. Chapter 11: Synthesis Strategies and Mechanisms

    • Retrosynthesis and planning synthesis
    • Key synthetic reactions and strategies
    • How mechanisms guide synthetic pathways

13. Chapter 12: Conclusion: Connecting Mechanisms to Organic Synthesis

    • How understanding mechanisms is crucial for successful organic synthesis
    • Practical application of reaction mechanisms in laboratory work

14. Appendix: Reaction Mechanism Summary Tables

    • Quick reference tables for common organic reaction mechanisms
    • Important tips for remembering and applying mechanisms

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